In nuclear engineering, the void coefficient (more properly called void coefficient of reactivity) is a number that can be used to estimate how much the reactivity of a nuclear reactor changes as voids (typically steam bubbles) form in the reactor moderator or coolant. Net reactivity in a reactor is the sum total of all these contributions, of which the void coefficient is but one. Reactors in which either the moderator or the coolant is a liquid typically will have a void coefficient value that is either negative (if the reactor is under-moderated) or positive (if the reactor is over-moderated). Reactors in which neither the moderator nor the coolant is a liquid (e.g., a graphite-moderated, gas-cooled reactor) will have a void coefficient value equal to zero. It is unclear how the definition of 'void' coefficient applies to reactors in which the moderator/coolant is neither liquid nor gas (supercritical water reactor).
https://en.wikipedia.org/wiki/Void_coefficient
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