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Wednesday, September 6, 2023

09-05-2023-2059 - draft (bromine, etc., draft)

Bromine, 35Br
Liquid and gas bromine inside transparent cube
Bromine
Pronunciation/ˈbrmn, -mɪn, -mn/ (BROH-meen, -⁠min, -⁠myne)
Appearancereddish-brown

Standard atomic weight Ar°(Br)

  • [79.90179.907]
  • 79.904±0.003 (abridged)[1]
Bromine in the periodic table
Hydrogen
Helium
Lithium Beryllium
Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium
Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium
Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium

Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Cl

Br

 I 
seleniumbrominekrypton
Atomic number (Z)35
Groupgroup 17 (halogens)
Periodperiod 4
Block  p-block
Electron configuration[Ar] 3d10 4s2 4p5
Electrons per shell2, 8, 18, 7
Physical properties
Phase at STPliquid
Melting point(Br2) 265.8 K ​(−7.2 °C, ​19 °F)
Boiling point(Br2) 332.0 K ​(58.8 °C, ​137.8 °F)
Density (near r.t.)Br2, liquid: 3.1028 g/cm3
Triple point265.90 K, ​5.8 kPa[2]
Critical point588 K, 10.34 MPa[2]
Heat of fusion(Br2) 10.571 kJ/mol
Heat of vaporisation(Br2) 29.96 kJ/mol
Molar heat capacity(Br2) 75.69 J/(mol·K)
Vapour pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 185 201 220 244 276 332
Atomic properties
Oxidation states−1, +1, 2,[3] +3, +4, +5, +7 (a strongly acidic oxide)
ElectronegativityPauling scale: 2.96
Ionisation energies
  • 1st: 1139.9 kJ/mol
  • 2nd: 2103 kJ/mol
  • 3rd: 3470 kJ/mol

Atomic radiusempirical: 120 pm
Covalent radius120±3 pm
Van der Waals radius185 pm
Color lines in a spectral range
Spectral lines of bromine
Other properties
Natural occurrenceprimordial
Crystal structureorthorhombic
Orthorhombic crystal structure for bromine
Speed of sound206 m/s (at 20 °C)
Thermal conductivity0.122 W/(m⋅K)
Electrical resistivity7.8×1010 Ω⋅m (at 20 °C)
Magnetic orderingdiamagnetic[4]
Molar magnetic susceptibility−56.4×10−6 cm3/mol[5]
CAS Number7726-95-6
History
Discovery and first isolationAntoine Jérôme Balard and Carl Jacob Löwig (1825)
Isotopes of bromine

Main isotopes[6] Decay

abun­dance half-life (t1/2) mode pro­duct
79Br 51% stable
81Br 49% stable
 Category: Bromine
| references

Bromine is a chemical element with the symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived from the Ancient Greek βρῶμος (bromos) meaning "stench", referring to its sharp and pungent smell.

Elemental bromine is very reactive and thus does not occur as a free element in nature. Instead, it can be isolated from colourless soluble crystalline mineral halide salts analogous to table salt, a property it shares with the other halogens. While it is rather rare in the Earth's crust, the high solubility of the bromide ion (Br) has caused its accumulation in the oceans. Commercially the element is easily extracted from brine evaporation ponds, mostly in the United States and Israel. The mass of bromine in the oceans is about one three-hundredth that of chlorine. 

https://en.wikipedia.org/wiki/Bromine

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