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Sunday, September 19, 2021

09-19-2021-1215 - drafting

Lavoisier's fundamental contributions to chemistry were a result of a conscious effort to fit all experiments into the framework of a single theory. He established the consistent use of the chemical balance, used oxygen to overthrow the phlogiston theory, and developed a new system of chemical nomenclature which held that oxygen was an essential constituent of all acids (which later turned out to be erroneous).
The result of this work was published in a memoir, "On Heat." Lavoisier and Laplace designed an ice calorimeter apparatus for measuring the amount of heat given off during combustion or respiration.
Lavoisier employed the new nomenclature in his Traité élémentaire de chimie (Elementary Treatise on Chemistry), published in 1789. This work represents the synthesis of Lavoisier's contribution to chemistry and can be considered the first modern textbook on the subject.
Lavoisier also did early research in physical chemistry and thermodynamics in joint experiments with Laplace. They used a calorimeter to estimate the heat evolved per unit of carbon dioxide produced, eventually finding the same ratio for a flame and animals, indicating that animals produced energy by a type of combustion reaction.
Lavoisier also contributed to early ideas on composition and chemical changes by stating the radical theory, believing that radicals, which function as a single group in a chemical process, combine with oxygen in reactions. He also introduced the possibility of allotropy in chemical elements when he discovered that diamond is a crystalline form of carbon.
He was also responsible for the construction of the gasometer, an expensive instrument he used at his demonstrations. While he used his gasometer exclusively for these, he also created smaller, cheaper, more practical gasometers that worked with a sufficient degree of precision that more chemists could recreate.[46]
He was essentially a theorist, and his great merit lay in his capacity to take over experimental work that others had carried out—without always adequately recognizing their claims—and by a rigorous logical procedure, reinforced by his own quantitative experiments, expounding the true explanation of the results.[citation needed] He completed the work of Black, Priestley and Cavendish, and gave a correct explanation of their experiments.
Overall, his contributions are considered the most important in advancing chemistry to the level reached in physics and mathematics during the 18th century.[47]
Lavoisier, together with Louis-Bernard Guyton de Morveau, Claude-Louis Berthollet, and Antoine François de Fourcroy, submitted a new program for the reforms of chemical nomenclature to the Academy in 1787, for there was virtually no rational system of chemical nomenclature at this time. This work, titled Méthode de nomenclature chimique (Method of Chemical Nomenclature, 1787), introduced a new system which was tied inextricably to Lavoisier's new oxygen theory of chemistry.[38] The Classical elements of earth, air, fire, and water were discarded, and instead some 55 substances which could not be decomposed into simpler substances by any known chemical means were provisionally listed as elements. The elements included light; caloric (matter of heat); the principles of oxygen, hydrogen, and azote (nitrogen); carbon; sulfur; phosphorus; the yet unknown "radicals" of muriatic acid (hydrochloric acid), boric acid, and "fluoric" acid; 17 metals; 5 earths (mainly oxides of yet unknown metals such as magnesia, baria, and strontia); three alkalies (potash, soda, and ammonia); and the "radicals" of 19 organic acids.
Lavoisier's researches included some of the first truly quantitative chemical experiments. He carefully weighed the reactants and products of a chemical reaction in a sealed glass vessel so that no gases could escape, which was a crucial step in the advancement of chemistry.[36] In 1774, he showed that, although matter can change its state in a chemical reaction, the total mass of matter is the same at the end as at the beginning of every chemical change. Thus, for instance, if a piece of wood is burned to ashes, the total mass remains unchanged if gaseous reactants and products are included. Lavoisier's experiments supported the law of conservation of mass. In France it is taught as Lavoisier's Law and is paraphrased from a statement in his Traité Élémentaire de Chimie: "Nothing is lost, nothing is created, everything is transformed." Mikhail Lomonosov (1711–1765) had previously expressed similar ideas in 1748 and proved them in experiments; others whose ideas pre-date the work of Lavoisier include Jean Rey (1583–1645), Joseph Black (1728–1799), and Henry Cavendish (1731–1810).[37
Lavoisier is commonly cited as a central contributor to the chemical revolution. His precise measurements and meticulous keeping of balance sheets throughout his experiment were vital to the widespread acceptance of the law of conservation of mass. His introduction of new terminology, a binomial system modeled after that of Linnaeus, also helps to mark the dramatic changes in the field which are referred to generally as the chemical revolution.
The same year he coined the name oxygen for this constituent of the air, from the Greek words meaning "acid former".[35][41] He was struck by the fact that the combustion products of such nonmetals as sulfur, phosphorus, charcoal, and nitrogen were acidic. He held that all acids contained oxygen and that oxygen was therefore the acidifying principle
Many investigators had been experimenting with the combination of Henry Cavendish's inflammable air, which Lavoisier termed hydrogen (Greek for "water-former"), with "dephlogisticated air" (air in the process of combustion, now known to be oxygen) by electrically sparking mixtures of the gases. All of the researchers noted Cavendish's production of pure water by burning hydrogen in oxygen, but they interpreted the reaction in varying ways within the framework of phlogiston theory. Lavoisier learned of Cavendish's experiment in June 1783 via Charles Blagden (before the results were published in 1784), and immediately recognized water as the oxide of a hydroelectric gas.[42]

https://en.wikipedia.org/wiki/Antoine_Lavoisier

About the time of his father's death, Cavendish began to work closely with Charles Blagden, an association that helped Blagden enter fully into London's scientific society. In return, Blagden helped to keep the world at a distance from Cavendish. Cavendish published no books and few papers, but he achieved much...Cavendish found that a definite, peculiar, and highly inflammable gas, which he referred to as "Inflammable Air", was produced by the action of certain acids on certain metals. This gas was hydrogen, which Cavendish correctly guessed was proportioned two to one in water.[6]
Cavendish's apparatus for making and collecting hydrogen[1]
https://en.wikipedia.org/wiki/Henry_Cavendish
https://en.wikipedia.org/wiki/Henry_Grey,_1st_Duke_of_Kent
https://en.wikipedia.org/wiki/Hydrogen_fuel

Torbern Olaf (Olof) Bergman (KVO) (20 March 1735 – 8 July 1784) was a Swedish chemist and mineralogist noted for his 1775 Dissertation on Elective Attractions, containing the largest chemical affinity tables ever published. Bergman was the first chemist to use the A, B, C, etc., system of notation for chemical species.

https://en.wikipedia.org/wiki/Torbern_Bergman

Thomas Charles Hope FRSE FRS PRCPE FFPSG(21 July 1766 – 13 June 1844) was a British physician, chemist and lecturer. He proved the existence of the element strontium,[2][3] and gave his name to Hope's Experiment, which shows that water reaches its maximum density at 4 °C (39 °F).[2]

https://en.wikipedia.org/wiki/Thomas_Charles_Hope

Edward Leamington Nichols (September 14, 1854 – November 10, 1937) was an American scientist. He was a physicist and astronomer,[2] professor of physics at Cornell University.[3]
https://en.wikipedia.org/wiki/Edward_Leamington_Nichols


https://en.wikipedia.org/wiki/Antoine_Lavoisier

https://en.wikipedia.org/wiki/Pierre-Simon_Laplace - French 1749 
https://en.wikipedia.org/wiki/Alessandro_Volta - Italy 1745 
https://en.wikipedia.org/wiki/William_Herschel - German 1738

https://en.wikipedia.org/wiki/Isaac_Newton 1643

https://en.wikipedia.org/wiki/Pendulum

https://en.wikipedia.org/wiki/Harmonic_oscillator

https://en.wikipedia.org/wiki/Christiaan_Huygens 1629



https://en.wikipedia.org/wiki/Robert_Hooke 1635 


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