The transition dipole moment or transition moment, usually denoted for a transition between an initial state, , and a final state, , is the electric dipole moment associated with the transition between the two states. In general the transition dipole moment is a complex vector quantity that includes the phase factors associated with the two states. Its direction gives the polarization of the transition, which determines how the system will interact with an electromagnetic wave of a given polarization, while the square of the magnitude gives the strength of the interaction due to the distribution of charge within the system. The SI unit of the transition dipole moment is the Coulomb-meter (Cm); a more conveniently sized unit is the Debye (D).
https://en.wikipedia.org/wiki/Transition_dipole_moment
Sunday, September 12, 2021
09-12-2021-0157 - Astrochemistry
Astrochemistry is the study of the abundance and reactions of molecules in the Universe, and their interaction with radiation.[1]The discipline is an overlap of astronomy and chemistry. The word "astrochemistry" may be applied to both the Solar System and the interstellar medium. The study of the abundance of elements and isotope ratios in Solar System objects, such as meteorites, is also called cosmochemistry, while the study of interstellar atoms and molecules and their interaction with radiation is sometimes called molecular astrophysics. The formation, atomic and chemical composition, evolution and fate of molecular gas clouds is of special interest, because it is from these clouds that solar systems form.
Observations of solar spectra as performed by Athanasius Kircher (1646), Jan Marek Marci (1648), Robert Boyle (1664), and Francesco Maria Grimaldi (1665) all predated Newton's 1666 work which established the spectral nature of light and resulted in the first spectroscope.[2] Spectroscopy was first used as an astronomical technique in 1802 with the experiments of William Hyde Wollaston, who built a spectrometer to observe the spectral lines present within solar radiation.[3] These spectral lines were later quantified through the work of Joseph Von Fraunhofer.
While radio astronomy was developed in the 1930s, it was not until 1937 that any substantial evidence arose for the conclusive identification of an interstellar molecule[6] – up until this point, the only chemical species known to exist in interstellar space were atomic. These findings were confirmed in 1940, when McKellar et al. identified and attributed spectroscopic lines in an as-of-then unidentified radio observation to CH and CN molecules in interstellar space.[7] In the thirty years afterwards, a small selection of other molecules were discovered in interstellar space: the most important being OH, discovered in 1963 and significant as a source of interstellar oxygen,[8] and H2CO (Formaldehyde), discovered in 1969 and significant for being the first observed organic, polyatomic molecule in interstellar space[9]
The discovery of interstellar formaldehyde – and later, other molecules with potential biological significance such as water or carbon monoxide – is seen by some as strong supporting evidence for abiogenetic theories of life: specifically, theories which hold that the basic molecular components of life came from extraterrestrial sources. This has prompted a still ongoing search for interstellar molecules which are either of direct biological importance – such as interstellar glycine, discovered in 2009[10] – or which exhibit biologically relevant properties like Chirality – an example of which (propylene oxide) was discovered in 2016[11] – alongside more basic astrochemical research.
Moreover, such methods are completely blind to molecules that have no dipole. For example, by far the most common molecule in the universe is H2 (hydrogen gas), but it does not have a dipole moment, so it is invisible to radio telescopes.
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