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Tuesday, September 28, 2021

09-27-2021-1811 - transition metal

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In chemistry, the term transition metal (or transition element) has three possible definitions:

  • The IUPAC definition[1] defines a transition metal as "an element whose atom has a partially filled  d sub-shell, or which can give rise to cations with an incomplete d sub-shell".
  • Many scientists describe a "transition metal" as any element in the d-block of the periodic table, which includes groups 3 to 12 on the periodic table.[2][3] In actual practice, the f-block lanthanide and actinideseries are also considered transition metals and are called "inner transition metals".
  • Cotton and Wilkinson[4] expand the brief IUPAC definition (see above) by specifying which elements are included. As well as the elements of groups 4 to 11, they add scandium and yttrium in group 3, which have a partially filled d sub-shell in the metallic state. Lanthanum and actinium, which they consider group 3 elements, are however classified as lanthanides and actinides respectively.

English chemist Charles Rugeley Bury (1890–1968) first used the word transition in this context in 1921, when he referred to a transition series of elements during the change of an inner layer of electrons (for example n = 3 in the 4th row of the periodic table) from a stable group of 8 to one of 18, or from 18 to 32.[5][6][7] These elements are now known as the d-block.

https://en.wikipedia.org/wiki/Transition_metal 


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